Mg-7Sn-Zn(Y)合金的显微组织、时效硬化行为及力学性能Microstructure, age-hardening behavior and mechanical properties of Mg-7Sn-Zn(Y) alloy
毕广利;徐作成;顾家睿;姜静;蒋春宏;李元东;
BI Guang-li;XU Zuo-cheng;GU Jia-rui;JIANG Jing;JIANG Chun-hong;LI Yuan-dong;State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals,Lanzhou Univ. of Tech.;Lanshi Foundry Co., Ltd.;
摘要(Abstract):
研究了Zn和Y合金化对Mg-7Sn合金显微组织、时效硬化行为和力学性能的影响.铸态Mg-7Sn合金主要由α-Mg和共晶(α-Mg+Mg_2Sn)相组成.Zn添加细化了Mg_2Sn相的尺寸,促进了Mg_2Sn相大量、均匀的弥散分布,同时诱导了Mg_2Sn相的非基面析出,增强了合金时效硬化效果.合金时效峰值硬度从64.6 HV增大到69.7 HV,峰值时效时间从166 h缩小至142 h.Zn和Y元素共同添加形成了针状MgSnY相,有效缩短了合金的时效峰值时间(由166 h缩短至120 h),但合金的峰值硬度略有降低,Mg-7Sn-1Zn合金具有最佳的力学性能,其高力学性能主要归结为细小、高体积分数Mg_2Sn相的析出强化.
The microstructure, age-hardening behavior and mechanical properties of Mg-7 Sn-Zn(Y) alloy were investigated. The as-cast Mg-7 Sn alloy was mainly composed of α-Mg and eutectic(α-Mg+Mg_2Sn) phase. The addition of Zn refines Mg_2Sn phase, increases volume fraction of Mg_2Sn phase and promotes precipitation of Mg_2Sn phase on non-basal plane, and thus enhances the ageing hardening capacity of the alloy. The peak-ageing hardness of the Mg-7 Sn-1 Zn alloy increases from 64.6 HV to 69.7 HV, and the peak-ageing time decreases from 166 h to 142 h. The addition of Zn and Y elements forms the needlelike MgSnY phase. Although the peak-ageing time of the alloy is effectively decreased(166 h to 120 h), the peak-ageing hardness of the alloy reduces. The Mg-7 Sn-1 Zn alloy exhibits the best mechanical properties, Which was mainly attributed to the precipitation strengthening of fine Mg_2Sn phase with high volume fraction.
关键词(KeyWords):
Mg-Sn-Zn-Y合金;显微组织;时效硬化行为;力学性能
Mg-Sn-Zn-Y alloy;microstructure;age-hardening behavior;mechanical properties
基金项目(Foundation): 国家自然科学基金(51961021);; 甘肃省自然科学基金(18JR3RA138);; 大学生创新创业计划(DC2018022,DC2019158,DC2019186)
作者(Author):
毕广利;徐作成;顾家睿;姜静;蒋春宏;李元东;
BI Guang-li;XU Zuo-cheng;GU Jia-rui;JIANG Jing;JIANG Chun-hong;LI Yuan-dong;State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals,Lanzhou Univ. of Tech.;Lanshi Foundry Co., Ltd.;
Email:
DOI:
参考文献(References):
- [1] 马颖,刘云坡,安凌云,等.三氧化钼和钼酸钠对镁合金微弧氧化膜的影响 [J].兰州理工大学学报,2018,44(3):6-11.
- [2] 马颖,朱文军,安凌云,等.不同电压下钼酸钠对镁合金微弧氧化膜的影响 [J].兰州理工大学学报,2018,44(1):1-5.
- [3] CHEN Yuan,WANG Yi,GAO Junjie.Microstructure and mechanical properties of as-cast Mg-Sn-Zn-Y alloys [J].Journal of Alloys and Compounds,2018,740(5):727-734.
- [4] ZHANG Jinghuai,LENG Zhe,LIU Shujuan,et al.Structure stability and mechanical properties of Mg-Al-based alloy modified with Y-rich and Ce-rich misch metals [J].Journal of Alloys and Compounds,2011,509:187-193.
- [5] WANG Xuejian,CHEN Zongning,REN Jing,et al.Corrosion behavior of as-cast Mg-5Sn based alloys with In additions in 3.5wt% NaCl solution [J].Corrosion Science,2019,164:108318.
- [6] HUANG Xufei,LI Hongjia,CAI Wupeng,et al.On the crystallographic features of Mn precipitates in a Mg-Sn-Mn alloy [J].Journal of Alloys and Compounds,2015,633(5):54-58.
- [7] JIANG Jing,LI Tingqu,BI Guangli,et al.Microstructure and mechanical properties of extruded Mg-7Sn-5Zn-xAl(x=0,1,2 and 3wt.%) alloy [J].Journal of Materials Engineering and Performance,2019,28:2672-2680.
- [8] LIU C Q,CHEN H W,Liu H,et al.Metastable precipitate phases in Mg-9.8wt%Sn alloy [J].Acta Materialia,2018,144(1):590-600.
- [9] YE Li,ZHUANG Yuanlin,ZHAO Dongshan,et al.Transmission electron microscopy investigations of the microstructures in rapidly solidified Mg-Sn ribbons [J].Micron,2018,115(5):1-6.
- [10] DEV A,NASKAR N,KUMAR N,et al.A systematic investigation of secondary phase dissolution in Mg-Sn alloys [J].Journal of Magnesium and Alloys,2019,7(4):725-737.
- [11] JIANG Jing,BI Guangli,ZHAO Lei,et al.Dry sliding wear behavior of extruded Mg-Sn-Yb alloy [J].Journal of Rare Earths,2015,33(1):77-85.
- [12] BI Guangli,XU Zuocheng,JIANG Jing,et al.High-speed impact behavior and microstructure evolution of an extruded Mg-7Sn-5Zn-3Al alloy [J].Journal of Materials Engineering and Performance,2020,29:6427-6438.
- [13] 徐春杰,代盼,屠涛,等.热处理对Mg-5Sn-1Si合金组织及硬度的影响 [J].材料热处理学报,2013,10:83-89.
- [14] SASAKI T T,OH-ISHI K,OHKUBO T,et al.Enhanced age hardening response by the addition of Zn in Mg-Sn alloys [J].Scripta Materialia,2006,55(3):251-254.
- [15] MENDIS C L,BETTLES C J,GIBSON M A,et al.An enhanced age hardening response in Mg-Sn based alloys containing Zn [J].Materials Science and Engineering A,2016,435-436(5):163-171.
- [16] MENDIS C L,BETTLES C J,GIBSON M A,et al.Refinement of precipitate distributions in an age-hardenable Mg-Sn alloy through microalloying [J].Philosophical Magazine Letters,2006,86(7):443-456.
- [17] BEHDAD S,ZHOU L,HENDERSON H B,et al.Improvement of aging kinetics and precipitate size refinement in Mg-Sn alloys by hafnium additions [J].Materials Science and Engineering A,2016,651(10):854-858.
- [18] HUANG X F,ZHANG W Z.Improved age-hardening behavior of Mg-Sn-Mn alloy by addition of Ag and Zn [J].Materials Science and Engineering A,2012,552(30):211-221.
- [19] ZHANG Duyao,QIU Dong,GIBSON Mark A,et al.Additive manufacturing of ultrafine-grained high-strength titanium alloys [J].Nature,2019,576(7785):91-95.
- [20] CHEN Yuan,LI Jin,SONG Yu,et al.Effect of Zn on microstructure and mechanical property of Mg-3Sn-1Al alloys [J].Materials Science and Engineering A,2014,612(26):96-101.
- [21] 苏娟,郭锋,蔡会生,等.Zn固溶量对Mg-Zn-Y合金组织的影响 [J].稀有金属材料与工程,2019,48(7):2179-2184.
- [22] WANG Jinhui,WEI Fuan,SHI Bo,et al.The effect of Y content on microstructure and tensile properties of the as-extruded Mg-1Al-xY alloy [J].Materials Science and Engineering A,2019,765(23):138288-138297.
- [23] LUO Kang,ZHANG Liang,WU Guohua,et al.Effect of Y and Gd content on the microstructure and mechanical properties of Mg-Y-RE alloys [J].Journal of Magnesium and Alloys,2019,7(2):345-354.
- [24] ZHONG Feng,WU Huaijie,JIAO Yunlei,et al.Effect of Y and Ce on the microstructure,mechanical properties and anisotropy of as-rolled Mg-8Li-1Al alloy [J].Journal of Materials Science and Technology,2020,39(15):124-134.
- [25] ZHAO Hongda,QIN Gaowu,REN Yuping,et al.Microstructure and tensile properties of as-extruded Mg-Sn-Y alloys [J].Transactions of Nonferrous Metals Society of China,2010,20(2):493-497.
- [26] HU Guangshan,ZHANG Dingfei,ZHAO Dingzang,et al.Microstructures and mechanical properties of extruded and aged Mg-Zn-Mn-Sn-Y alloys [J].Transactions of Nonferrous Metals Society of China,2014,24(10):3070-3075.
- [27] LIU X J,KAINUMA R,WANG C P,et al.Experimental investigation and thermodynamic calculation of the phase equilibria in the Cu-Sn and Cu-Sn-Mn systems [J].Metallurgical & Materials Transactions A,2004,35(6):1641-1654.
- [28] HUANG X F,FU B Q,HUANG W G.Newly observed irrational crystall ographic features of non-basal Mg2Sn prccipitates in a Mg-4Sn alloy aged at 160 ℃ [J].Journal of Materials Science and Technology,2021,77:237-243.
- [29] NIE J F,GAO X,ZHU S M,et al.Enhanced age hardening response and creep resistance of Mg-Gd alloys containing Zn [J].Scripta Materialia,2005,53(9):1049-1053.
- [30] LIU Chaoqiang,CHEN Houwen,NIE Jianfeng,et al.Interphase boundary segregation of Zn in Mg-Sn-Zn alloys [J].Scripta Materialia,2016,123(4):5-8.
- 毕广利
- 徐作成
- 顾家睿
- 姜静
- 蒋春宏
- 李元东
BI Guang-li- XU Zuo-cheng
- GU Jia-rui
- JIANG Jing
- JIANG Chun-hong
- LI Yuan-dong
- State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals
- Lanzhou Univ. of Tech.
- Lanshi Foundry Co.
- Ltd.
- 毕广利
- 徐作成
- 顾家睿
- 姜静
- 蒋春宏
- 李元东
BI Guang-li- XU Zuo-cheng
- GU Jia-rui
- JIANG Jing
- JIANG Chun-hong
- LI Yuan-dong
- State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals
- Lanzhou Univ. of Tech.
- Lanshi Foundry Co.
- Ltd.